Two-photon induced isomerization through a cyaninic molecular antenna in azo compounds

نویسندگان

چکیده

Upon two photon excitation, energy migration from the antenna-localized second singlet excited state to stilbenyl-azopyrrole section allows for efficient indirect excitation and phototransformation of this actuator.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Two-photon absorption spectrum in diazoaromatic compounds

This Letter studies the degenerate two-photon absorption (2PA) spectra of three diazoaromatic compounds using Z-scan with fs-pulses. The 2PA spectra exhibit resonant enhancement of the nonlinearity as the excitation approaches the linear absorption. The absence of 2PA to the pp band is related to the weaker donor/acceptor groups, and lower symmetry of diazoaromatic compounds, in agreement with ...

متن کامل

Ultrafast deactivation of bilirubin: dark intermediates and two-photon isomerization.

Bilirubin is a neurotoxic product responsible for neonatal jaundice, which is generally treated by phototherapy. The photoreaction involves ultrafast internal conversion via an elusive intermediate and Z-E isomerization with minor yield (less than 3% in solution). The structure of the intermediate remains unclear. Here, the combination of UV-vis and mid-IR ultrafast transient absorption spectro...

متن کامل

Human infrared vision is triggered by two-photon chromophore isomerization.

Vision relies on photoactivation of visual pigments in rod and cone photoreceptor cells of the retina. The human eye structure and the absorption spectra of pigments limit our visual perception of light. Our visual perception is most responsive to stimulating light in the 400- to 720-nm (visible) range. First, we demonstrate by psychophysical experiments that humans can perceive infrared laser ...

متن کامل

Anticancer phototherapy using activation of E-combretastatins by two-photon-induced isomerization.

The photoisomerization of relatively nontoxic E-combretastatins to clinically active Z-isomers is shown to occur in solution through both one- and two-photon excitations at 340 and 625 nm, respectively. The photoisomerization is also demonstrated to induce mammalian cell death by a two-photon absorption process at 625 nm. Unlike conventional photodynamic therapy (PDT), the mechanism of photoiso...

متن کامل

Azo mesogenic compounds

Series of elongated azo esters containing three rings with methyl moiety as one of the terminal carbon chain and various substituents R(R=H,CH3,OCH3,NO2,Cl) at the other end of the molecule have been isolated , and their structure were were characterized by H-NMR and IR as well as elemental analysis . The mesomorphic properties of these compounds were investigated via differential scanning calo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Chemical Communications

سال: 2021

ISSN: ['1359-7345', '1364-548X']

DOI: https://doi.org/10.1039/d0cc08346a